FERROELECTRIC NANOCOMPOSITES WITH GOVERNED INTERFACE ON BASE OF MAGNETIC POROUS GLASSES

Authors

  • Aleksandr Naberezhnov Ioffe  Institute, 26 Polytekhnicheskaya str., St. Petersburg, 194021, Russian Federation (RU)
  • Anna Sysoeva Ioffe  Institute, 26 Polytekhnicheskaya str., St. Petersburg, 194021, Russian Federation (RU)
  • Olga Alekseeva Peter the Great St. Petersburg Polytechnic University 29 Politechnicheskaya str., St. Petersburg, 195251, Russian Federation (RU)
  • Polina Vanina Peter the Great St. Petersburg Polytechnic University 29 Politechnicheskaya str., St. Petersburg, 195251, Russian Federation (RU)
  • I. Golosovsky Petersburg Nuclear Physics Institute named by B.P. Konstantinov of NRC «Kurchatov Institute» (RU)
  • Bernard Nacke Leibniz University of Hannover, ETP, Wilhelm-Busch-Street, 30167 Hannover, Germany (DE)
  • Alexander Nikanorov Leibniz University of Hannover, ETP, Wilhelm-Busch-Street, 30167 Hannover, Germany (DE)

DOI:

https://doi.org/10.17770/etr2019vol3.4048

Keywords:

magnetic glasses, nanocomposite materials, restricted geometry, interface, artificial multiferroics

Abstract

Two-phase (nonporous) magnetic alkali borosilicate glasses have been produced by induction melting. Their macroscopic properties and crystal structure have been studied and it is shown that in the silica skeleton there are the agglomerates of Fe3O4. These agglomerates are formed by monodomain nanoparticles of magnetite and demonstrate the superparamagnetic properties. After special thermal treatment (liquation process) and chemical etching the nanoporous matrices with random dendrite pore structure and magnetic properties have been produced. The channels (porous space) were filled by ferroelectric materials KH2PO4 (KDP), KH2PO4+(NH4)H2PO4 (KDP-ADP or KADP), and NaNO2 and the effect of applied magnetic fields on phase transitions in these nanocomposite have been studied. It has also been established that a restricted geometry changed essentially the phase diagram of KADP.

 

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References

A. Mekki, G. D. Khattak, D. Holland, M. Chinkhota, and L. E. Wenger, “Structure and magnetic properties of vanadiumsodium silicate glasses,” Journal of Non-Crystalline Solids, vol. 318, no. 1-2, pp. 193–201, 2003.

J. Zhou, W. Wu, D. Caruntu, M. H. Yu, A. Martin, J. F. Chen, C. J. O'Connor and W. L. Zhou, “Synthesis of porous magnetic hollow silica nanospheres for nanomedicine application,” Journal of Physical Chemistry C, vol. 111, no. 47, pp. 17473–17477, 2007.

S. Tomas, D. Sakthikumar, Y. Yoshida and M. R. Anantharaman, “Spectroscopic and photoluminescence studies on optically transparent magnetic nanocomposites based on sol-gel glass: Fe3O4,” Journal of Nanoparticle Research, vol. 10, no. 1, pp. 203–206, 2008.

C.-C. Chang, L. Zhao and M.-K. Wu, “Magnetodielectric study in SiO2-coated Fe3O4 nanoparticle compacts,” Journal of Applied Physics, vol. 108, no. 9, Article ID 094105, 2010.

O. Yeshchenko, I. Dmitruk, A. Alexeenko, A. Dmytruk and V. Tinkov, “Optical properties of sol-gel fabricated Co/SiO2 nanocomposites,” Physica E: Low-Dimensional Systems and Nanostructures, vol. 41, no. 1, pp. 60–65, 2008.

T. V. Antropova, I. N. Anfimova, I. V. Golosovsky, Yu. A. Kibalin, A. A. Naberezhnov, N. I. Porechnaya, O. A. Pshenko and A. V. Filimonov “Structure of Magnetic Nanoclusters in Ferriferous Alkali Borosilicate Glasses,” Physics of the Solid State, vol. 54, no. 10, pp. 2110–2115, 2012.

T. Senoy, D. Sakthikumar, Y. Yoshida and M.R. Anantharaman, “Spectroscopic and Photoluminescence studies on optically transparent magnetic nanocomposites based on sol–gel glass: Fe3O4 ,“ Journal of Nanoparticle Research, vol. 10, no.1, pp. 203-206, 2008.

S. Huang, C. Li, Z. Cheng, Y. Fan, P. Yang, C. Zhang, K. Yang and J. Lin, “Magnetic Fe3O4 - mesoporous silica composites for drug delivery and bioadsorption,” Journal of Colloid and Interface Science, vol. 376, no. 1, pp. 312-321, 2012.

S. Zhu, Z. Zhou and D. Zhang, “Control of Drug Release through the In Situ Assembly of Stimuli- Responsive Ordered Mesoporous Silica with Magnetic Particles,” Journal ChemPhysChem., vol. 8, pp. 2478 – 2483, 2007.

R.K. Singh, A. Srinivasan and G.P. Kothiyal, “Evaluation of CaO–SiO2–P2O5–Na2O–Fe2O3 bioglass-ceramics for hyperthermia application,” Journal of Material Science: Materials in Medicine, vol. 20, pp. S147-S151, 2009.

X. Li, F. Qu, W. Li, H. Lin and Y. Jin, “Synthesis of hierarchically porous bioactive glasses using natural plants as template for bone tissue regeneration,” Journal of Sol-Gel Science and Technology, vol. 63, no. 3, pp. 416–424, 2012.

Y.-H. Won, H.S. Jang, S.M. Kim, E. Stach, M. Ganesana, S. Andreescu and L.A. Stanciuet, “Biomagnetic glasses: preparation, characterization, and biosensor applications,” Langmuir, vol. 26, no. 6, pp. 4320–4326, 2010.

C.A. Paula, P.C.A. Jerónimo, N. Alberto, A.N. Araújo, M. Conceição, B.S.M. Montenegro, “Optical sensors and biosensors based on sol–gel films,” Talanta, vol. 72, no. 1, pp. 13-27, 2007.

C.-C. Chang, L. Zhao and M.-K. Wu, “Magnetodielectric study in SiO2-coated Fe3O4 nanoparticle compacts,” Journal of Applied Physics, vol. 108, article #094105, 5 pp, 2010.

S.V. Stolyar, I.N. Anfimova, I.A. Drozdova and T.V. Antropova, “The new two-phase ferriferous alkali borosilicate

glasses for creation of the nanoporous materials with magnetic properties,” Nanosist., Nanomater., Nanotechnol., vol. 9, no. 2, pp. 433-440, 2011.

A. Naberezhnov, N. Porechnaya, V. Nizhankovskii, A. Filimonov and B. Nacke, “Morphology and magnetic properties of ferriferous two-phase sodium borosilicate glasses,” The Scientifc World Journal, vol. 2014, Article ID 320451, 7 pp, 2014.

A.A. Naberezhnov, E.Yu. Koroleva, A.V. Filimonov, A.I. Rudskoy, B. Nacke, V. Kichigin and V. Nizhankovskii, “Production of magnetic alkali-borosilicate glasses by induction melting,” Metal Science and Heat Treatment, vol. 56, no. 11 – 12, pp. 681-684, 2015.

A.V. Filimonov, A.I. Rudskoy , A.A. Naberezhnov, S.B. Vakhrushev, A.E. Fotiadi , E.Yu. Koroleva, I.V. Golosovsky, Yu.A. Kumzerov, B. Nacke, "Nanocomposite materials on the base of dielectric porous matrices", St.-Petersburg State Polytechnical University Journal. Physics and Mathematics, vol. 4 - 2 (182), pp. 9 -29, 2013

W.F. Brown, “Magnetic interactions of superparamagnetic particles,” Journal of Applied Physics, vol. 38, no. 3, pp. 1017–1018, 1967.

N. Andreeva, M. Tomkovich, A. Naberezhnov, B. Nacke, A. Filimonov, O. Alekseeva, P. Vanina and V. Nizhankovskii, “SEM and AFM Studies of Two-Phase Magnetic Alkali Borosilicate Glasses,” The Scientific World Journal, vol. 2017, Article ID 9078152, 9 pp, 2017.

S.A. Gridnev, L.N. Korotkov, S.P. Rogova, L.A. Shuvalov and R.M. Fedosyuk, “Dielectric properties and x-T phase diagram of K1-x(NH4)xH2PO4 crystals,” Ferroelectrcis Letters, vol. 13, no. 3, pp. 67-72, 1991.

L.N. Korotkov and L.A. Shuvalov, “Transitions to the relaxor and dipole glass states in mixed crystals of the potassium dihydrogen phosphate family,” Crystallography reports, vol. 49, no. 5, pp. 832-842, 2004.

E.Yu. Koroleva, A.A. Naberezhnov, V.I. Nizhankovskii and N.I. Porechnaya, “Magnetostriction and Magnetization of ferriferous glasses,” St. Petersburg State Polytechnical University Journal. Physics and Mathematics, vol. 170, no. 2, pp. 144 - 148, 2013. [in Russian]

M.P. Shaskolskaya, “Acoustic crystals,” Moscow. Nauka, 633 pp, 1982. [in Russian]

A.I. Nikitchenko, A.V. Azovtsev and N.A. Pertsev, “Phase diagrams of ferroelectric nanocrystals strained by an elastic matrix,” Journal of Physics: Condensed Matter, vol. 30, 015701 (9 pp.), 2018.

A. da Costa Lamas, S.-L. Chang, S. Caticha-Ellis. “On the Use of Powder Difractometry in the Study of Phase Transitions”, Physica Status Solidi (a), vol. 68, pp. 173-178, 1981

A. Naberezhnov, A. Fokin, Yu. Kumzerov , A. Sotnikov , S. Vakhrushev, and B. Dorner, “Structure and properties of confined sodium nitrite”, Eur. Phys. Jour. E. vol. 12, pp. s21-s24, 2003

A. I. Beskrovny, S. G. Vasilovskiі, S. B. Vakhrushev, D. A. Kurdyukov, O. I. Zvorykina, A. A. Naberezhnov, N. M. Okuneva, M. Tovar, E. Rysiakiewicz-Pasek, and P. Jagus “Temperature Dependences of the Order Parameter for Sodium Nitrite Embedded into Porous Glasses and Opals” Physics of the Solid State, vol. 52, no.5, pp. 1092–1097, 2010

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Published

2019-06-20

How to Cite

[1]
A. Naberezhnov, “FERROELECTRIC NANOCOMPOSITES WITH GOVERNED INTERFACE ON BASE OF MAGNETIC POROUS GLASSES”, ETR, vol. 3, pp. 172–176, Jun. 2019, doi: 10.17770/etr2019vol3.4048.